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Though I have no experience doing this, there are many threads online and a fair number mention having an additional sound card.
One of the threads says that if you're using a USB connection (and from what I see your G930s are wireless), then it's possible to have Vent coming through the headset while other sound comes through the speakers, though this isn't 100% consistent across all programs.
I think the long and short of it is that you can't have one sound device routing some sound to your headset and the rest to your speakers.
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