Or, hear me out.
Don't spend £100 on a 10+ year old PSU.
It's a waste of £100 regardless of how long he's planning on using it.
A literal 1050 W ATX 3.1 rated PSU is £121.
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Excellent 850 W ATX 3.0/3.1 rated options exist for cheaper or slightly more expensive than £100.
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Every single one of these options has at least one 16 pin native connector.
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The entry price is: £90-121.
£100 is not a "saving" of £40, or £20, it's £100 down the drain.
This might sound harsh but this is an excellent example of trying to make use of a "deal" that actually results in money down the drain. The tier of the PSU when it was new is completely irrelevant, it's a 10 year old PSU. That is the stat that is relevant.
For something like, IDK, maybe £40, you could argue "OK, this is probably better than a £40 new PSU", which also won't be ATX 3.0/3.1 certified, but it's still a risk, as it's a
10 year old used PSU.
But £100?