That H100i should and does handle that CPU fine. My H100i still cooled my CPU fine while it was consuming over 300 Watts so that 220Watts should be totally OK.
What AI suite shows here is the socket temperature, which can get a bit hot because this socket and VRM area doesn't really have a lot of ventilation going on.
Heat from both the CPU and the VRM tends to build up in the socket, even when the CPU is properly cooled. This doesn't really matter as both parts are designed with these temperatures in mind and wont degrade as a result of these temperatures(close/over 100 degrees would've been a different matter).
If you want to lower those temperatures, there is a simple way: place a fan over the VRM and or socket.
(My sabertooth with an 8350 at 4,8GHz cooled by an H100i)
This for me helps a great deal when in comes to lowering those temperatures, especially when overclocking loads.