FSB speed is this FSB strap to north bridge?
Alternatives are: Auto, 200, 266, 333, 400
And this is the other setting?
DRAM Frequency:
Auto, 533, 639, 667, 709, 800, 852, 887, 1066, 1200
That CPU's default is 266 (333 and 400 are overclocks). In that generation, FSB speed is linked to CPU speed, so if you change it, you also change the CPU clock (and it might not like that)
Basically, if you somehow manage to get it to run at 400, that would been 3600 Mhz max speed, it runs hotter than the sun at that speed. But it can be done with a good chip...
So don't touch the FSB, leave it at Auto or 266
Instead, those RAM frequencies are various multipliers (seems that your bios made it easier, instead of using 2x, 2.5x, 3x... etc., as RAM must work in sync with the FSB (that was the architecture back then).
533 = 2x
667 = 2.5x
800 = 3x
887 = 3.5x
I have no idea what others are, half-steps ?
In any case, if your RAM and CPU gets too hot at 800, simply downclock it at 667... the difference in performance will be minor
DDR2 uses 1.5v at JEDEC speed (667 being the max), make sure you set that one. SPD might have set it to 1.8v, causing it to run very hot.
Of course, trial and error is your best friend.
Don't be afraid, you won't burn anything by downclocking and downvolting. It's the other direction that causes magic smoke

The worse that could happen is the computer not booting or crashing in Windows.