When a computer does a calculation and cannot get the same answer twice, that is a problem. That is what it means when ThrottleStop starts reporting errors in the TS Bench test.
2 + 5 = 7
2 + 5 = 9
Should I keep them this way?
Reducing your undervolt a little was a wise decision. Some computers might be very stable for a long time even though they are slowly churning out errors like above. Over time, Windows or any of your files can become corrupted. Some users only judge stability based on if their computer crashes while playing a game. I do important stuff like programming ThrottleStop on my computer. A few errors like above could take me weeks or months to troubleshoot. I prefer that my computer is as close to 100% stable as possible. The TS Bench has proven to be a good quick test when adjusting offset voltages. It can report errors long before a computer crashes. It is best not to ignore any errors that the TS Bench reports.
The core and cache offset voltages do not need to be set equal to each other. Some users have had success by using a slightly higher offset undervolt for the core compared to the cache. If the cache is stable at -100 mV then combine that with the core set to -125 mV or -150 mV. Run the TS Bench to see if this is stable. After that, run Cinebench R23 while using different voltages for a comparison. Older 8th Gen CPUs used to benefit from using different voltages. Set the Cinebench R23 Minimum Test Duration to Off so it only runs a single test at a time. If you do not see any improvement in performance or in your temperatures when running different voltages then set them equally.
It is OK to use ThrottleStop to lower your maximum CPU temperature. I always like to see maximum performance but like you, I hate listening to loud, high speed fans that are in most laptops. That is why I like using my very quiet desktop computer. It runs cool and performs well at low noise levels. Hard to fit in my backpack though.
Edit - The moment you see any errors in the TS Bench test, I would stop it immediately. Even 1 error means that this test has told you what you need to know. Your voltage is not 100% stable so your undervolt should be reduced.