I actually did unplug my PSU, i turned it off and completely unplugged the cord. it turned on for half a second afterward when i was plugging in my 24pin, I decided to reapply new thermal paste as it has been a while and my temps were starting to increase.So you didn't unplug the power supply from the wall before even thinking about reaching inside the case? Did you touch bare metal of the case interior to discharge any static in your body before touching the cooler or reapplying the new TIM (thermal interface material)?
I would not recommend that. Lighter fluid is a petroleum by-product and therefore, will leave a residue film. And if accidently spilled, could easily eat away at many plastics (such as the CPU socket or materials in many components) or the protective resin coatings applied to PCBs.
I recommend 91-93% isopropyl alcohol - available at most pharmacies - for cleaning off old TIM.
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Why did you feel the need to apply new TIM in the first place? Unless the cured bond between the mating surfaces is broken, there is no reason to replace it just because it is X number of years old. Not one TIM maker, cooler maker, CPU maker, motherboard maker recommends replacing TIM just because a certain amount of time has passed. TIM can easily last 5, 10, 15 years or long AS LONG AS the cured bond is not broken.
And it is important to remember the purpose of TIM is to fill the microscopic pits and valleys in the mating surfaces - pushing out any insulating air. The only reason TIM comes in a semi-liquid form is so it can easily be squeezed out of the tube and evenly spread across the die. So even if the TIM dries out, the solids left behind are still occupying those pits and valleys, preventing any insulating air from seeping back in.
If you "need" the few degrees a fresh new layer of TIM might provide to keep from crossing over thermal protection thresholds, you have bigger cooling issues to deal with - like insufficient case cooling.