The video was quite well-made and interesting, but ultimately I agree with the commenters (many far more informed than I) who believe the video is misleading--perhaps deliberately so.
For der8auer, the video was certainly successful. It has gone about as viral as a video about PC water-cooling (a very niche topic) can go with over 87,000 views, and seemingly everyone is talking about it. Based on comments, most viewers seem to be persuaded. There are some areas of the video which strike me as being deliberately misleading (more on that latter), but I'm not sure what his monetary interest in that would be because he works for Thermal Grizzly, a company that does not sell coolant. Perhaps Thermal Grizzly and Aquacomputer have a relationship?
The basic theme of the video is to show
CHEMICAL CORROSION while talking about
GALVANIC CORROSION. These are not the same thing, full stop.
In the test a nickel-plated copper waterblock is submerged in distilled water. The container is left exposed to the atmosphere and heated to 60°C (140°F). From high school chemistry, we hopefully remember that heat speeds up chemical reactions. I am not a chemist, but I believe this would do two things for the test:
- It would accelerate the formation of carbonic acid in the water, lowering its pH (making it more acidic) quickly
- It would accelerate the acid-induced chemical corrosion of the submerged part
This test is
not representative of conditions in a PC water-cooling loop. First, a PC water-cooling loop is a closed system and will have limited exposure to carbon dioxide and thus limited formation of carbonic acid. Second, the ΔT of the liquid cooling medium in most PC water-cooling systems is a few degrees over ambient temperature at most. Therefore the pH of the water is unlikely to drop far below neutral, and chemical corrosion will not be sped up by heat.
His chemical corrosion test also just showed that some copper gets deposited onto the nickel plate....not exactly a cause for concern, is it? Earlier he tries to scare people by noting that calcium hydrogen carbonate will deposit limestone onto surfaces, but of course this isn't present in distilled water and will not form in it from the ions or oxides it grabs from metals present in water-cooling loops (it is, however, an excellent reason not to use tap water).
Then we get to what investors call
spreading FUD (fear, uncertainty, and doubt). The main way in which he spreads FUD is talking about galvanic corrosion, which is again something his test did not demonstrate. Galvanic corrosion is of course a legitimate concern and why so many posters here have talked about never mixing metals. der8auer doubles down on this FUD by suggesting (as some commenters here agreed with) that mixing metals in a water-cooling loop is inevitable by talking about brass fittings.
Here is where he gets really shady, and it's why I think he may be deliberately misleading his viewers. der8auer notes a couple of times that brass has zinc in it, and then he warns people that the electropotential of zinc is very different from copper. True enough, but brass is an
ALLOY whose electropotential is known. In fact, the electropotential of brass is almost identical to copper!
der8auer clearly isn't stupid, and neither are the engineers at Thermal Grizzly. Do they really think that the electropotential of zinc itself as opposed to brass is relevant here?
He also brought up distro plates, suggesting that they may have stainless steel in them. There are many types of stainless (usually in consumer applications something known as 304 or 18-8 is used), and while this isn't nearly as different from copper and common cupric alloys as aluminum is, there is
some difference.
Since he's German, here's a datasheet for an Alphacool distro:
https://download.alphacool.com/data...ate_360_Left_with_VPP_Apex_pump_datasheet.pdf
No stainless steel. Appears to be plastic with chrome-plated brass fittings. But yes, maybe someone makes a stainless steel distro plate.
So to summarize this video der8auer:
- Conducts a completely unrepresentative test that shows chemical corrosion
- Suggests how this shows the dangers of galvanic corrosion
- Misrepresents the galvanic corrosion potential in a typical PC water-cooling loop
I think that his video can be safely dismissed and that water-cooling enthusiasts who aren't mixing cupric and aluminum parts can continue using nothing but distilled water in their loops, especially if they sterilize (boiling works just fine) prior to assembly and fill.
Now...does this mean that you should
ONLY use distilled water and that this is
ALWAYS best? Not necessarily.
While looking into this, I found two articles that are over two decades old on Overclockers.com. They're still relevant today.
The first article deals with cooling relevant properties of water including:
- Viscosity
- Thermal Conductivity
- Specific Heat
- pH
- Conductivity
It also looks at different types of water and finds that regular distilled water from the grocery store is pretty good.
The second article deals with common additives to coolant loops such as:
- Corrosion inhibitors (and pH buffers)
- Surfactants
- Biocides
- Antifreeze
In the first article, the author observes that while "fresh" distilled water tends to have a relatively neutral pH that due to the absorption of carbon dioxide from the air it will over time become slightly acidic. He provides these figures:
The figures in the second table are ostensibly taken by testing the pH of liquid in an actual reservoir. Unfortunately time in the loop isn't given, but at any rate it does seem that distilled water in your cooling loop will become at least slightly acidic. The author notes that most coolants tend to become slightly acidic over time, and this is certainly true in the automotive world. Car mechanics will usually pH test your coolant and tell you that it's time to replace it once it becomes acidic.
While pH 6.22 water circulating at 25°C is not going to produce the chemical corrosion seen in der8auer's misleading video, perhaps it's doing something. Someone should empirically test this. If anyone reading has a pure distilled water cooling loop, please test the pH and report its value to us and the time that the water has been in your loop.
The author also makes the claim that an alkaline environment will retard the growth of biological organisms. In addition to not being a chemist, I am also not a biologist, but I think this claim is true.
This suggests that
SODIUM CARBONATE (aka "washing soda") would make a good additive to distilled water. It is alkaline, soluble, cheap, and safe for humans.
Biocides have obvious value, but may not be
necessary. Distilled water should not have biological organisms in it, nor should newly manufactured inorganic materials. You can further reduce risk by boiling the water and the loop parts. While those silver kill coils seem neat, they're probably not a great idea due to their electropotential. It's a pity everyone nickel plates now, because copper itself is actually quite biocidal. If you combine a carefully sterilized loop with an alkaline coolant, then biocide would appear to be superfluous. Still, it's unlikely to
hurt and gives peace of mind, so not a bad idea..
Broad spectrum corrosion inhibitors like the benzotriazole present in DP Plus seem like a good idea, at least for some. If you fail to notice that your pH is dropping, or you don't
really know what metals are in your loop, this will help you.
Antifreeze seems like a poor idea. The function of antifreeze is prevent coolant from freezing or boiling. PC water-cooling loops run near ambient temperature and neither are a risk. Ethylene glycol will increase the viscosity of the coolant and reduce its specific heat capacity. Thus you reduce cooling performance for no benefit. It is toxic and thus biocidal, but a more concentrated biocide would provide the same benefit without reducing coolant performance. If you're running a chiller and do need the antifreeze protection, methanol may be a better idea. It is even less viscous than water and has slightly higher specific heat capacity than ethylene glycol.
Most interesting to me is the idea of adding
surfactants. I'll quote the author directly:
Surfactants (Surface Active Agents)
Surfactants (also known as wetting agents) decrease water’s natural surface tension. High surface tension causes water to be attracted to itself, which is why water beads-up on a slick surface. Surfactants are used in PC water-cooling systems to promote better heat transfer. They do this in several ways:
First, by reducing the surface tension, water can better wet the inside surfaces of waterblocks and radiators (get down into all the little cracks and crevices), which potentially leads to better heat transfer. Second, reducing the surface tension also helps release numerous tiny air bubbles that build up and become trapped on internal surfaces (microscopic air bubbles block heat flow). Third, as we mentioned earlier, reducing the surface tension can lower the viscosity of water slightly.
Household soap and detergent products (like Dawn liquid dishwashing detergent) are surfactants but should only be used in very small amounts if added to your PC’s coolant system (~2 drops per gallon). These products generally contain other additives (emulsifiers, sudsing agents, perfumes, etc.) that are not beneficial for PC water-cooling applications.
There are many different kinds of surfactants. Soaps fall into one class of surfactants (anionic) made from animal fats and vegetable oils. Detergents on the other hand include several types of surfactants (anionic and nonionic) made primarily from petrochemicals.
Surfactants are organic molecules, composed of two parts. On one end is a carboxylate group (alkylated carboxylic acid) and on the other end is a long straight hydrocarbon chain. The carboxylate end is attracted to water. This is the (hydrophilic – water-loving) end. The hydrocarbon chain end is repelled by water (hydrophobic – water-hating) but is attracted to other molecules and surfaces.
When a surfactant is added to water, it acts as a “bridge”, which allows the water to fully wet or spread out along a surface that might otherwise repel the water molecules. It is this same wetting ability of soaps and detergents that allows water to attach and suspend oil and grease for cleaning.
So at least in theory the addition of surfactants can enhance the performance coolant. I'd like to see some empirical data on this along with a recommendation of what to use.
What have I learned?
- der8auer is deceptive
- Chemical corrosion is a minor issue and best dealt with by making your coolant slightly basic
- Galvanic corrosion is an overblown problem if you don't put aluminum into your system
- Some additives are at least in principle meritorious
I have never built a water-cooled PC and started to become very interested in the idea this year. So this has all been very interesting and informative to me. Thank you to everyone who posted in this thread!