Are you running any manufacturer's control software on your computer? MSI Control Center or anything similar?
Post some more screenshots so I can see what CPU you have and tell me what computer you have. Show me the main TS window, the TPL and FIVR windows. If the turbo ratio limits are being manipulated by something on your computer, maybe you will need to lower the Speed Shift Max value in the TPL window to try and control your maximum CPU speed and temps.
I will send you an updated beta version of ThrottleStop you can try.